As a general note, having a chracter that is aligned to more than one realm is not only possible, but not too rare an occurrence. As a matter of fact, the ArM rulebook, discussng realm-power interactions, amkes the example of an hermetic mage who also has a faerie power of illusion and an infernal gift of causing sickness. Such characters may occur because of two typical causes: either the character has two different powers (typically Supernatural Abilities or magic) coming from two different realms, or the character has one or more virtues causing his magic to be aligned with one or two additional realms of power. Both cases may arise either because the virtues or powers were thrusted on their character without his choice (i.e. they were an inborn talent, or powerful denizens of the realm chose the grant them for their own purposes) or they were actively sought by the character via Mystery initiation or enrollment in a group.
It is clear that a character having affiliation with two different realms (or three, for a magus) should be adequately justified by background, but it is also clear that either of both of the above mechanisms may justify such a character: e.g. the character may have one affiliation as an inborn talent or heritage, and the other being the result of purposeful mystery initiation. Or the other affiliation having been given as a boon, curse, or temptation, or a tool for redemption.
To sum it up: it is not something I would expect to see too frequently, but with the right background, I would not have problems in allowing uch a character.
E.g. Divine + Faerie Magics: a maga that was raised by a Merinita parens, then develops an interest in reattuning herself and her magic with the divine. Otherwise, a holy magus that is granted affinity of his magic with the faerie realm, too, as a boon by a powerful faerie. In current edition, the divine is not assumed to be ineherently antagonistic to magic and faerie. It all rests on how such a character sees his rapport with the divine: it may be that he sees reconciling faerie and magical powers and beings with the divine as his mission.
Divine + Infernal magics: in this case, the realms are indeed antagonistic, so in order to justify such a character, it would be necessary for either of these affinities to have been gained by the character without her will or cognizance, or her having undergone some kind of convernsion in the past: e.g. the magus raised by a diabolist parens that sought holy magic initatin to redeem and cleanse his magic. Or a holy maga being "gifted" infernal powers by demons as a tool for temptation and corruption.
As a matter of fact, I'm currently planning such a character: a merinita theurgist pagan magus that has both Faerie Magic and Chtonic Magic. In his case, the former would come by his initation in merinita mysteries, with the latter would represent his affinity with the most dark and primal aspects of magic , man, and nature, rather than the infernal and demons in a strict sense. The various affiliations of the character would IC be seen as being in tune with different parts of the pagan mysticism: the "bright", more benevolent or distant forces and deities (theurgy and faerie magic) and the "dark", more malevolent ones (chtonic magic). Of course, this idea might be modified, and the chtonic bit dropped, if it appeared (I have yet to receive RoP:I) that chtonic magic represents attunement with the infernal and demons in a strict judeo-christian sense, since the concept of the character is that of a pagan mystic that i equally and deeply in tune with the magic and faerie sides of pagan spirituality. the chtonic bit is a sidenote to remark that pagan mysticism would also include dealings and affinities with forces (the "chtonic" deities of earth, death, darkness in a proper sense) that divine religions would see as "demonic".