So... say we have a magus, with Potent Magic. He invents a potent version of Pilum of Fire with a staff as a casting item, giving him a +3 bonus to spell (project a bolt or other missile). He then enchants his staff as a talisman and attunes his talisman for a +3 bonus to project a bolt or other missile.
When casting his potent Pilum of Fire while holding his talisman staff does he a) get a +3 bonus to casting or b) get a +6 bonus to casting?
Just remember that the bonus from Potent Magic is limited only by Magic Theory score, while the talisman is [strike]also[/strike] limited to a single bonus (the highest single bonus) [strike]as well as MT score[/strike].